KEY WORDS: ZONING, HEAVY METALS, PLAIN, GROUNDWATER

INTRODUCTION

Generally, the processes of harvesting, refining, trans- port and consumption of oil has severe pollution poten- tial and, if discharged to the environment, it results in severe contamination of soil, air, surface and ground-

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Received 2nd June, 2016

Accepted after revision 25th June, 2016 BBRC Print ISSN: 0974-6455 Online ISSN: 2321-4007

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water. Generally, oil spills on land which penetrate into the ground water issue is not a new issue any more. In Iran, due to the presence of fuel tanks, contamination of groundwater aquifers, petroleum and behavior of pollut- ants is important. Considering the fact that in addition to the majority of agricultural land irrigated by under-

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Leila Rostami Bairagh and Fatemeh Nasehi

ground wells, are used for drinking (Asadollah Fardi, 2010). Water is the most important inorganic compound for living cells and life of all living things depend on it. Today, with the population growth, reducing pollution and increasing per capita water conservation physical, chemical and biological water, the water crisis has been proposed as one of the major worldwide problem (Min- istry of Health and Medical Education Department of Health, 2010 and Dabiri, 2013).

Especially in recent decades, the most important con- cern of people living on Earth, especially in arid and semi-arid countries such as Iran, is the issue of water supply with appropriate quality and quantity. On the other hand, there are focuses on increasing public sensi- tivity and awareness about the environment and achieve sustainable development. Thus, a balance between envi- ronmental goals and comprehensive approach to water quality prior conditions, along with its quantity has been required (Rezaei, 2011).

Water pollution is the result of the addition of any foreign body in such a way that the quality of its physi- cal, chemical or biological change it so that it could be harmful for human consumption and agriculture and other creatures and man cannot even ordinary water treatment, water supply to provide its own life. In other words, when water is contaminated or its composition, either directly or indirectly as a result of human activity changed and this change will cause other than that for applications that previously could not be used in normal mode (Fataei, 2011).

Access to safe drinking water is an essential require- ment of any society. Population growth, expanding cit- ies and industries etc. has caused the pollution of the environment, especially water resources for drinking (Hajizadeh, 1998). Groundwater pollution is one of the most important environmental issues of geology, espe- cially in areas where surface water exist or are lacking. Unfortunately, due to the invisibility of groundwater, a lot of people about their importance and they are not aware of the harmful effects of environmental pollution (Davis, 1994). The number of combinations for elements of heavy metal toxicity mineral known for years. These materials contain the most toxic materials in the envi- ronment, including lead, mercury, cadmium and nickel. These metals accumulate in living organisms and remain for a long time as the sum of the toxin acts (Dabiri, 2013).

Heavy metals as a result of weathering of rocks and soil and volcanic activity and human ecosystems to find their ways (Khatami, 2007). Cyclical changes and chemi- cal point of view, having regular control program to pre- dict the water quality of the river seems necessary. In addition to the detection and characterization of small pollution sources for effective control of contaminants

and the proper management of water resources is essen- tial (Listory, 1990). In a study of Malakoutian et al con- ducted in 2014 as arsenic concentrations of heavy met- als cadmium, lead and copper in drinking water supplies in rural southeastern plains of Rafsanjan, stated that the contaminants in the water that excessive amounts of heavy metals which makes the development of various diseases and in all cases of lead and cadmium is above the standard level, (Malakoutian et al 2014).

In another study of Eghbali Shams Abadi et al (2010) conducted on heavy elements chromium, cadmium, lead and organic matter in the White River with a view of the structural geological origin, the workers stated cadmium and lead concentrations were close to limit or more, the study of industrial activities and urban and rural sewage discharge due to pollution of river sediments to determine cadmium and lead. Due to the large area and multiple sources of hazardous wastewater discharges to groundwater with heavy metals in this area and in parts of the aquifer is quite uncertain. On the other hand a large proportion of industrial wastewater is mainly in the fields of Karaj Special Road and Old Road, where wastewater discharged to surface, flows through local rivers fed by underground water leaks, so there is no information about the infected zones. Necessary meas- ures in this regard, and with little information regarding the use of new research in this area and use GIS tools will have to be developed.

MATERIAL AND METHODS

INTRODUCTION OF THE STUDY AREA

Tehran and Shahriar basin plains is located in north cen- tral Iranian plateau. The basin in the 45-51 45- ° 50 ‘east longitude coordinates 15 - ° 35 north latitudes to 15-36. The study area includes plains aquifer and Shahriar Tehran are the sum of a unit at the complex hydrologi- cal and hydraulic connection with each other. In order to explain the characteristics and identifying and distin- guishing them individually to explain the details of each of aquifers and then provide a map of the integrated water these features is an evaluated. In Figure 1, sche- matic position three regions aquifer is presented.

In this study, the study area was divided using the network almost to a 59 network. In each grid or a pixel sampling stations (as much as possible from the net- work) is selected and a total of 59 networks and 59 sam- pling stations in the selected area, in addition to network dimensions are 5 × 5 meters. This type of study is ana- lytical. Chemical analysis results in Excel as a database was saved. Position wells were recorded using GPS for maps and entered into the Arc GIS software.

RESULTS AND DISCUSSION

ZONING MAPS OF THE STUDY AREA

Investigation of zoning maps of heavy metals cadmium, cobalt, copper, lead, chromium in Tehran - Karaj plain after reviewing the most optimal interpolation algorithm zoning map of the concentration of ions, cadmium, cobalt, lead, chromium was prepared using Arc GIS soft- ware. Figures (3) to (10) map of the location and amounts of heavy metals in the study area shows changes in both spring and summer.

Map prepared based on cadmium on hand to high- water seasons suggest that the rate of metal concen- trations in groundwater in the range of 0.082 to 28.9 micrograms per liter. In other words, a large part of the plains in the high water has a concentration less than the limit specified in the WHO (0.003) drinking water standard of Iran (0.01), however, southern parts of the greater concentration.

Rezvani et al (2013) found similar results in a study were similar in Eshtehard plain. Map prepared based on cadmium concentration of Karaj plain blue for low seasons suggest that the rate of metal concentrations

in groundwater in the range of 0.053 to 17.5 micro- grams per liter. In other words, a large part of plain water in low season with less than the maximum per- missible concentration determined in the WHO (0.003) drinking water standard Iran (0.01), however, southern parts of the greater concentration. In addition to the plain of the disease than seasonal high water pollu-

tion has been reduced and the area less than plain on the seasons of the year have been infected. However, the wet season and low water contamination in almost the same way. It seems disposal of wastewater from the wells, causing a sharp increase in the concentration of cadmium in groundwater in the southern extent of the plain.

MAP OF COBALT CONCENTRATION FOR HIGH- WATER AND LOW-WATER SEASONS

Due to the lack determine the maximum allowable con- centration of cobalt metal underground water standards, there is no contamination on the plains; however, in the southern extent of the plain for both seasons, sharp increase of cobalt concentration is observed which is mainly caused by groundwater discharge of sewage and industrial workshops. Map prepared based on cobalt concentration in the hands of Tehran-Karaj plain for high-water seasons suggest that the rate of metal con- centrations in groundwater in the range of 0.05 to 259 micrograms per liter. In other words, a large part of the plains in the high water season has low concentration, however, the southern part of plain has more concentra- tion. In addition plain disease severity has been reduced than the seasonal high water pollution. These changes are slight changes, especially in the southwestern part of the plain area of less than plain on the seasons of the year have been infected. However, the wet season and low water pollution in quite the same way. Map pre- pared based on cobalt concentration in Karaj plain for low-water seasons suggest that the rate of metal con- centrations in groundwater in the range of 0.03 to 164 micrograms per liter.

MAP OF LEAD CONCENTRATIONS FOR HIGH- WATER AND LOW-WATER SEASONS

Map of lead concentrations of Karaj plain aquifer indicate that the vast majority far from if or in other words is very low. However, in the southern part of the border and out of plain concentrations of this element out of Iran and the World Health Organization standard is extremely high. This situation is true both for high-water and low-water seasons. However, in seasons of low water pollution has been reduced in view of the plain area. In other words, the area contaminated areas is greater than the area of polluted areas in the high water season in low water season and vice versa. Map prepared based on the concentration of lead in Karaj plain for high-water seasons indicate that the concentrations of these metals in groundwater in the range of 0.01 to 198 micrograms per liter and for low-water seasons in the concentration range is 0.005 to 129.

MAP OF COPPER CONCENTRATION FOR HIGH- WATER AND LOW-WATER SEASONS

Map of copper concentration in Karaj plain didn’t show that significant emissions but the zoning maps show abnormal increase is observed in the southern part of

the plain. Workshop industrial site in south and disposal of sewage and paint manufacturing foundries through absorption and enter groundwater through wells has been increasing copper concentration in these sectors. Map prepared based on copper concentrations of Karaj plain in high-water seasons indicates that the metal concentrations in groundwater suggest that the rate ranging from zero to 24 milligrams per liter. In other words, a large part of the plains in the high water has lower concentrations particularly northern parts, however, the southern plains has low concentration. In addition plain disease severity has been reduced to the seasonal high water pollution, despite these changes, particularly changes in the southern part of the plain area of less than plain on the seasons of the year have been infected. However, the high-water and low-water seasons pollution in quite the same way. Map prepared based on copper concentrations in Tehran-Karaj plain were also evaluated for low-water seasons and indicate that the concentrations of these metals in groundwater in the range of zero to 15 milligrams per liter.

CONCLUSION

Investigation of groundwater of Tehran-Karaj plain was made from an environmental standpoint. In view of the heavy metal concentration maps of interpolated sam- pling points were observed, and found that south of the plains is seen in terms of emissions above the average standard of the World Health Organization. Map pre- pared based on cadmium concentration in the hands of the low-water seasons indicates that the concentra- tions of these metals in groundwater are in the range of 0.082 to 28.9 micrograms per liter. The concentration of cadmium in Tehran – Karaj plain for low-water sea- sons indicates that the concentrations of these metals in groundwater is in the range of 0.053 to 17.5 micrograms per liter. It seems sewage disposal equipment through absorption wells has caused a sharp increase in the con- centration of cadmium in groundwater in the southern extent of the plain. Cobalt concentration in Karaj plain to high water seasons suggest that the rate of metal con- centrations in groundwater in the range of 0.05 to 259 micrograms per liter. Cobalt concentration of Karaj plain blue for low seasons suggest that the rate of metal con- centrations in groundwater in the range of 0.03 to 164 micrograms per liter. Lead concentrations in water of Karaj plain to high-water seasons of metal concentra- tions in groundwater suggest that the rate of up to 198 micrograms per liter in the range of 0.01 to 0.005 to 129 of low water seasons concentration is in this range. Copper concentrations of Karaj plain for high-water

Leila Rostami Bairagh and Fatemeh Nasehi

seasons indicate that the concentrations of these metals in groundwater in the range of zero to 24 milligrams per liter. Copper concentrations in Karaj plain also were investigated for low-water seasons and indicate that the concentrations of these metals in groundwater in the range of zero to 15 milligrams per liter. The results of the surveys indicate that plain pollution with heavy metals is not a hazard but in areas of severe changes in some metals is visible.

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